Download e-book for kindle: Dynamics and Mechanisms of Photoinduced Electron Transfer by Noboru Matage, Tadashi Okada, N. Mataga, T. Okada, H.

By Noboru Matage, Tadashi Okada, N. Mataga, T. Okada, H. Masuhara

ISBN-10: 0444891919

ISBN-13: 9780444891914

This e-book comprises papers which research basic elements of photoinduced electron move reactions, a space within which a few breakthroughs have lately happened. The publication is split into 4 parts.

Parts I and II are often taken with the basic facets of the inter- and intra-molecular cost move, electron move and comparable phenomena reminiscent of solvent results, solvation dynamics, power hole dependences and radical pair dynamics. half III is anxious with electron move and effort move phenomena in polymers, motion pictures, crystals, and different limited platforms. partly IV, the mechanisms of the strength and electron move in organic photosynthetic platforms, proteins and response middle structures are discussed.

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Extra resources for Dynamics and Mechanisms of Photoinduced Electron Transfer and Related Phenomena

Example text

Using v m ax we were able to extract the appropriate potential parameters from the experimental study of Kjaer and Ulstrup. x Dynamics and Mechanisms of Photoinduced Transfer and Related Phenomena N. Mataga, T. Okada and H. V. All rights reserved. 39 Solvent Dynamics and Charge Transfer Reactions 3 a b Barton B . S m i t h , H y u n g J. K i m , Daniel B o r g i s and J a m e s T . H y n e s a a D e p a r t m e n t of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215, U S A b L a b o r a t o i r e de Physique Theorique des Liquides,Universite Pierre et Marie Curie,75252 Paris Cedex 0 5 , F R A N C E Abstract A brief account is given of s o m e highlights of recent studies of the influence of solvation dynamics for assorted charge transfer reactions.

W e thank E. Carter, D . Zichi, G. Ciccotti and M . Ferrario for collaboration on earlier aspects of s o m e of the topics discussed. H'lil! ΤΓΠΤ '///////////MM (A) 'IlilllllllllH Minium u minimi π Ίΐιιιιιιιιι ι illinium ι ///mini11 ///mm 11 ι mimt ι w \ ,/////! I I \ \ r/n ι \ \ \ \ ili'llll' ^' 1 ι \ ι \ \ \ y ; \\\\\\\% / , ι / / , , , . 5 Figure 1 1 . Calculated free energy c o n t o u r m a p in s and r for the t-BuCl s y s t e m in C H 3 C N [9]. 1 e V . T h e free energy value for the contour in the upper center is -3 e V .

R e s . 21 (1988) 128. F. Barbara, W . Jarzeba, A d v . Photochem. 15 (1990) 1. (c) M. Maroncelli, J. R. Fleming, Science 243 (1988) 1674. T. H y n e s , J. Phys. C h e m . 9 0 (1986) 3 7 0 1 . 3 L . D . Z u s m a n , C h e m . P h y s . 4 9 (1980) 2 9 5 . ibid. 8 0 (1983) 2 9 . ibid. 119 (1988) 5 1 . 4 B . R. F l e m i n g , J. Phys. Chem. 9 4 (1990) 9. J. E. M c M a n i s III, A c c . C h e m . Res. 2 3 (1990) 294. 6 I. Rips, J. Klafter, J. Jortner, J. Phys. C h e m . 9 4 (1990) 8557. 7 H. A.

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Dynamics and Mechanisms of Photoinduced Electron Transfer and Related Phenomena by Noboru Matage, Tadashi Okada, N. Mataga, T. Okada, H. Masuhara


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