Get Metallocenes in Regio- and Stereoselective Synthesis PDF

By Tamotsu Takahashi, K. Kanno, C. Kendall, M. Kotora, Z. Li, E. Negishi, N. Suzuki, T. Takahashi, T. Tan, P. Wipf, Z. Xi

ISBN-10: 3540016066

ISBN-13: 9783540016069

Content material: 1. creation -- 2. normal houses of Organometallic Complexes -- three. steel Alkyls, Aryls, and Hydrides and comparable [actual image now not reproducible]-Bonded Ligands -- four. Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions -- five. Complexes of [actual image no longer reproducible]-Bound Ligands -- 6. Oxidative Addition and Reductive removal -- 7. Insertion and removing -- eight. Nucleophilic and Electrophilic Addition and Abstraction -- nine. Homogeneous Catalysis -- 10. actual equipment in Organometallic Chemistry -- eleven. Metal-Ligand a number of Bonds -- 12. functions of Organometallic Chemistry -- thirteen. Clusters, Nanoparticles, fabrics, and Surfaces -- 14. purposes to natural Synthesis -- 15. Paramagnetic, High-Oxidation-State, and High-Coordination-Number Complexes -- sixteen. Bioorganometallic Chemistry -- worthwhile Texts on Allied themes -- significant response kinds

Show description

Read Online or Download Metallocenes in Regio- and Stereoselective Synthesis PDF

Similar metallurgy books

Download e-book for kindle: Corrosion Resistance of Aluminum and Magnesium Alloys: by Edward Ghali

Worthy details on corrosion basics and purposes of aluminum and magnesiumAluminum and magnesium alloys are receiving elevated cognizance because of their mild weight, abundance, and resistance to corrosion. specifically, whilst utilized in vehicle production, those alloys promise diminished motor vehicle weights, reduce gas intake, and ensuing environmental advantages.

Download PDF by Vistasp M. Karbhari: Rehabilitation of metallic civil infrastructure using fiber

Fiber-reinforced polymer (FRP) composites have gotten more and more renowned as a cloth for rehabilitating getting older and broken buildings. Rehabilitation of metal Civil Infrastructure utilizing Fiber-Reinforced Polymer (FRP) Composites explores using fiber-reinforced composites for boosting the steadiness and lengthening the lifetime of steel infrastructure equivalent to bridges.

K De Smet, P. N. Campbell, C Van Der Straeten's The hip resurfacing handbook : a practical guide for the use PDF

Hip resurfacing arthroplasty (HRA) utilizing metal-on-metal bearings is a longtime yet specialized approach in joint surgical procedure. in accordance with the event of prime specialists within the box, The hip resurfacing instruction manual presents a finished reference for all elements of this significant strategy. the 1st a part of the e-book studies and compares all of the significant hip resurfacing prostheses, their key layout good points, proper surgical strategies and scientific effects.

Soldering : understanding the basics - download pdf or read online

This booklet covers a variety of soldering equipment and methods in addition to the most recent details on solder alloys, solder movies, floor practise, fluxes and cleansing tools, heating equipment, inspection options, and qc and reliability. it's aimed toward for scientists, fabric engineers, designers, production engineers, and technologists who want functional advice instead of theoretical guide.

Extra resources for Metallocenes in Regio- and Stereoselective Synthesis

Example text

Treatment of zirconocene(II) species, generated in situ either by Cp2ZrCl2/2 n-BuLi (Negishi reagent) or Cp2ZrCl2/Mg/HgCl2, with a diene, a nonconjugated enyne, or a diyne affords high yield formation of corresponding bicyclic zirconacyclopentane, zirconacyclopentene, and zirconacyclopentadiene, respectively (Eqs. 15–18) [10, 15–17]. Titanacyclopentadienes could be prepared in a similar way [18, 19]. It is noteworthy that terminal acetylenes are generally not applicable for this reaction. Messy mixtures are normally obtained.

Hydroacylation . . . . . . . . . Hydroboration . . . . . . . . . Hydrosilylation . . . . . . . . . Hydration of Alkynes . . . . . . . Intramolecular Addition of Alcohols to Alkynes Allylic Amination . . . . . . . . Reaction of Diazocompounds with C=X Bonds . . . . . . . . 60 60 67 69 72 72 74 74 75 77 78 79 79 80 81 3 Coupling of Two or More Multiple Bonds . . . . . . . . . . 11 Coupling of Alkenes . . . . . . . . . . . .

133 Abstract Transition metal cyclopentadienyl complexes constitute a large family of compounds that can be used as catalyst for a number of organic transformations such as additions of various organics to double and triple bonds, inter- and intramolecular coupling of double and triple bonds, substitution reactions, functional group interconversions, isomerizations, and C–C bond cleavage reactions. These reactions usually proceed with high degree of regio-, stereo- and enantioselectivity under mild reaction conditions.

Download PDF sample

Metallocenes in Regio- and Stereoselective Synthesis by Tamotsu Takahashi, K. Kanno, C. Kendall, M. Kotora, Z. Li, E. Negishi, N. Suzuki, T. Takahashi, T. Tan, P. Wipf, Z. Xi

by Steven

Rated 4.87 of 5 – based on 30 votes