By Tamotsu Takahashi, K. Kanno, C. Kendall, M. Kotora, Z. Li, E. Negishi, N. Suzuki, T. Takahashi, T. Tan, P. Wipf, Z. Xi
Content material: 1. creation -- 2. normal houses of Organometallic Complexes -- three. steel Alkyls, Aryls, and Hydrides and comparable [actual image now not reproducible]-Bonded Ligands -- four. Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions -- five. Complexes of [actual image no longer reproducible]-Bound Ligands -- 6. Oxidative Addition and Reductive removal -- 7. Insertion and removing -- eight. Nucleophilic and Electrophilic Addition and Abstraction -- nine. Homogeneous Catalysis -- 10. actual equipment in Organometallic Chemistry -- eleven. Metal-Ligand a number of Bonds -- 12. functions of Organometallic Chemistry -- thirteen. Clusters, Nanoparticles, fabrics, and Surfaces -- 14. purposes to natural Synthesis -- 15. Paramagnetic, High-Oxidation-State, and High-Coordination-Number Complexes -- sixteen. Bioorganometallic Chemistry -- worthwhile Texts on Allied themes -- significant response kinds
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Extra resources for Metallocenes in Regio- and Stereoselective Synthesis
Treatment of zirconocene(II) species, generated in situ either by Cp2ZrCl2/2 n-BuLi (Negishi reagent) or Cp2ZrCl2/Mg/HgCl2, with a diene, a nonconjugated enyne, or a diyne affords high yield formation of corresponding bicyclic zirconacyclopentane, zirconacyclopentene, and zirconacyclopentadiene, respectively (Eqs. 15–18) [10, 15–17]. Titanacyclopentadienes could be prepared in a similar way [18, 19]. It is noteworthy that terminal acetylenes are generally not applicable for this reaction. Messy mixtures are normally obtained.
Hydroacylation . . . . . . . . . Hydroboration . . . . . . . . . Hydrosilylation . . . . . . . . . Hydration of Alkynes . . . . . . . Intramolecular Addition of Alcohols to Alkynes Allylic Amination . . . . . . . . Reaction of Diazocompounds with C=X Bonds . . . . . . . . 60 60 67 69 72 72 74 74 75 77 78 79 79 80 81 3 Coupling of Two or More Multiple Bonds . . . . . . . . . . 11 Coupling of Alkenes . . . . . . . . . . . .
133 Abstract Transition metal cyclopentadienyl complexes constitute a large family of compounds that can be used as catalyst for a number of organic transformations such as additions of various organics to double and triple bonds, inter- and intramolecular coupling of double and triple bonds, substitution reactions, functional group interconversions, isomerizations, and C–C bond cleavage reactions. These reactions usually proceed with high degree of regio-, stereo- and enantioselectivity under mild reaction conditions.
Metallocenes in Regio- and Stereoselective Synthesis by Tamotsu Takahashi, K. Kanno, C. Kendall, M. Kotora, Z. Li, E. Negishi, N. Suzuki, T. Takahashi, T. Tan, P. Wipf, Z. Xi